A review of chemistry, extraction, functional properties, and sustainable food applications of rambutan (Nephelium lappaceum L.)

Volume 3, Issue 2, Article Number: 262004 (2026)

👁 Views: 11 | ⬇ Downloads: 1

Sherin Mary Simon1,2,*  ORCID logo | Jyotsna Dayma3 ORCID logo

1School of Basic and Applied Science, Nirwan University, Jaipur 303305, Rajasthan (India)

2Department of Food Processing Technology, St. Teresa’s College (Autonomous) Ernakulam 682016, Kerala (India)

3School of Agricultural Sciences, Nirwan University, Jaipur 303305, Rajasthan (India)

Received: 04 August 2026 | Revised: 25 August 2026

Accepted: 29 August 2026 | Published Online: 10 September 2026

DOI: https://doi.org/10.5281/zenodo.22258347

© 2026 The Authors, under a Creative Commons license, Published by Scholarly Publication

Abstract

Rambutan (Nephelium lappaceum L.), a delicious tropical fruit, is cultivated extensively in the Southeast Asian region. Processing of rambutan generates a lot of seed waste as seeds are discarded when the edible portion of the fruit is stripped off. On an average, rambutan seeds form 5-10% of the total mass of the fruit. The kernel contained within the seeds, which is a fatty tissue extracted for its valuable content, contains about 30-40% of fat on a dry weight basis. A range of 20-41% has been mentioned in the literature due to variation in seed fraction, cultivar, and extraction process utilized for fat extraction from the kernels. Though considered a waste product, rambutan seeds are rich sources of edible fat. It is rich in oleic and arachidic acids, which give it unique physicochemical properties. These properties are similar to those of cocoa butter, making rambutan seed fat a promising ingredient for food applications.

This review summarizes the current knowledge on rambutan seeds as an underutilized agro-industrial by-product. It highlights their chemical composition, methods of fat extraction, physicochemical properties and potential food applications. The review discusses conventional extraction methods such as mechanical pressing extraction and solvent extraction. It also reviews new green extraction technologies such as supercritical CO2 extraction, ultrasound-assisted extraction, microwave-assisted extraction, and enzyme-assisted extraction. The review also describes the thermal behavior, crystallization, triacylglycerol profile, polymorphism and structural features of rambutan seed fat by using different analytical methods.

The functional attributes of rambutan seed fat, including its flexibility, oxidative stability, melting behavior, and emulsifying properties, are also evaluated in this research. Additionally, nutritional value, safety, and presence of antinutritional components of rambutan seed fat are also discussed. The study highlights the significance of using rambutan seed waste as a valuable resource rather than discarding it. It demonstrates how the circular economy and waste valorization are supported by the use of rambutan seed waste. Additionally, this method contributes to the Sustainable Development Goals (SDG) of the United Nations.

Keywords

Rambutan seed fat, Nephelium lappaceum, cocoa butter substitute, seed waste valorization, extraction technology, fat crystallization, circular economy

References

  • Afzaal, M., Saeed, F., Bibi, M., Ejaz, A., Shah, Y. A., Faisal, Z., Ateeq, H., Akram, N., Asghar, A., & Shah, M. A. (2023). Nutritional, pharmaceutical, and functional aspects of rambutan in industrial perspective: An updated review. Food Science & Nutrition, 11, 3675-3685.

[View Article]      [Google Scholar]

  • Beckett, S. T. (2008). Industrial chocolate manufacture and use (4th ed.). John Wiley & Sons, Ltd.

[View Book]        [Google Scholar]

  • Bhat, R. S., & Al-Daihan, S. (2014). Antimicrobial activity of Litchi chinensis and Nephelium lappaceum aqueous seed extracts against some pathogenic bacterial strains. Journal of King Saud University – Science, 26, 79-82.

[View Article]      [Google Scholar]

  • Chai, K. F., Adzahan, N. M., Karim, R., Rukayadi, Y., & Ghazali, H. M. (2019). Fat properties and antinutrient content of rambutan (Nephelium lappaceum L.) seed during solid-state fermentation of rambutan fruit. Food Chemistry, 274, 808–815.

[View Article]      [Google Scholar]

  • Datta, B., Buehler, M. J., Chow, Y., Gligorić, K., Jurafsky, D., Kaplan, D. L., Ledesma-Amaro, R., Del Missier, G., Neidhardt, L., Pichara, K., Sanchez-Lengeling, B., Schlangen, M., St. Pierre, S. R., Tagkopoulos, I., Thomas, A., Watson, N. J., & Kuhl, E. (2026). Artificial intelligence for food innovation. Nature Food, 7, 644–654.

[View Article]      [Google Scholar]

  • Declerck, A., Nelis, V., Danthine, S., Dewettinck, K., & Van der Meeren, P. (2021). Characterisation of fat crystal polymorphism in cocoa butter by time‑domain NMR and DSC deconvolution. Foods, 10, 520.

[View Article]      [Google Scholar]

  • Gbashi, S., & Njobeh, P. B. (2024). Enhancing food integrity through artificial intelligence and machine learning: A comprehensive review. Applied Sciences, 14, 3421.

[View Article]      [Google Scholar]

  • Hernandez-Hernandez, C., Aguilar, C. N., Rodriguez-Herrera, R., Flores-Gallegos, A. C., Morlett-Chavez, J., Govea-Salas, M., & Ascacio-Valdes, J. A. (2019). Rambutan (Nephelium lappaceum L.): Nutritional and functional properties. Trends in Food Science & Technology, 85, 201-210.

[View Article]      [Google Scholar]

  • Issara, U., Zzaman, W., & Yang, T. A. (2014). Rambutan seed fat as a potential source of cocoa butter substitute in confectionary product. International Food Research Journal21, 25-31.

[View PDF]         [Google Scholar]

  • Jahurul, M. H. A., Azzatul, F. S., Sharifudin, M. S., Norliza, M. J., Hasmadi, M., Lee, J. S., Patricia, M., Jinap, S., George, M. R., Khan, M. F., & Zaidul, I. S. M. (2020). Functional and nutritional properties of rambutan (Nephelium lappaceum L.) seed and its industrial application: A review. Trends in Food Science & Technology, 99, 367-374.

[View Article]      [Google Scholar]

  • Kaushik, R., Morya, S., Bashir, O., Bhadha, J. H., & Kasankala, L. M. (2025). Valorization of fruit waste through reutilization approach: A comprehensive review. eFood, 6, e70073.

[View Article]      [Google Scholar]

  • Khairy, H. L., Saadoon, A. F., Zzaman, W., Yang, T. A., & Mat Easa, A. (2018). Identification of flavor compounds in rambutan seed fat and its mixture with cocoa butter determined by SPME-GCMS. Journal of King Saud University – Science, 30, 316–323.

[View Article]      [Google Scholar]

  • Kumar, H., Kimta, N., Guleria, S., Cimler, R., Sethi, N., Dhanjal, D. S., Singh, R., Duggal, S., Verma, R., Prerna, Pathera, A. K., Alomar, S. Y., & Kuca, K. (2024). Valorization of non-edible fruit seeds into valuable products: A sustainable approach towards circular bioeconomy. Science of the Total Environment, 922, 171142.

[View Article]      [Google Scholar]

  • Kumar, M., Sharma, K., & Bangar, S. P. (Eds.). (2024). Valorization of fruit seed waste from food processing industry: Insights on nutritional profile, biological functions, and applications. Elsevier.

[Google Scholar]

  • Le, Q., Fang, Z., Chen, H., & Wu, J. (2025). Comprehensive review on oleogels structured by lipid-based compounds: From structure mechanisms to nutritional functionalities and applications in food industry. Comprehensive Reviews in Food Science and Food Safety, 24, e70214.

[View Article]      [Google Scholar]

  • Mahisanunt, B., Jom, K. N., Matsukawa, S., & Klinkesorn, U. (2017). Solvent fractionation of rambutan (Nephelium lappaceum L.) kernel fat for production of non-hydrogenated solid fat: Influence of time and solvent type. Journal of King Saud University-Science29, 32-46.

[View Article]      [Google Scholar]

  • Nastić, N., Mazumder, J. A., & Banat, F. (2025). Supercritical CO2 extraction of oil from fruit seed by‑product: Advances, challenges, and pathways to commercial viability. Critical Reviews in Food Science and Nutrition, 66, 589–606.

[View Article]      [Google Scholar]

  • Ray, J., Smith, K. W., Bhaggan, K., & Stapley, A. G. F. (2022). Crystallization and polymorphism of cocoa butter equivalents from blends of palm mid fraction and hard stearins produced by enzymatic acidolysis of high oleic sunflower oil. European Journal of Lipid Science and Technology, 124, 2100228.

[View Article]      [Google Scholar]

  • Rodríguez-Blázquez, S., Gómez-Mejía, E., Rosales-Conrado, N., & León-González, M. E. (2025). Recent insights into eco-friendly extraction techniques for obtaining bioactive compounds from fruit seed oils. Foods, 14, 2271.

[View Article]      [Google Scholar]

  • Sirisompong, W., Jirapakkul, W., & Klinkesorn, U. (2011). Response surface optimization and characteristics of rambutan (Nephelium lappaceum L.) kernel fat by hexane extraction. LWT – Food Science and Technology, 44, 1946-1951.

[View Article]      [Google Scholar]

  • Solis-Fuentes, J. A., Camey-Ortiz, G., Hernandez-Medel, M. R., Perez-Mendoza, F., & Duran-de-Bazua, C. (2010). Composition, phase behavior and thermal stability of natural edible fat from rambutan (Nephelium lappaceum L.) seed. Bioresource Technology, 101, 799-803.

[View Article]      [Google Scholar]

  • Sonwai, S., Kaphueakngam, P., & Flood, A. (2014). Blending of mango kernel fat and palm oil mid-fraction to obtain cocoa butter equivalent. Journal of Food Science and Technology, 51, 2357-2369.

[View Article]      [Google Scholar]

  • Thilakarathna, R. C. N., Siow, L. F., Tang, T. K., & Lee, Y. Y. (2023). A review on application of ultrasound and ultrasound assisted technology for seed oil extraction. Journal of Food Science and Technology, 60, 1222–1236.

[View Article]      [Google Scholar]

  • Thitilertdecha, N., Teerawutgulrag, A., & Rakariyatham, N. (2008). Antioxidant and antibacterial activities of Nephelium lappaceum L. extracts. LWT – Food Science and Technology, 41, 2029-2035.

[View Article]      [Google Scholar]

  • Tripathi, P., & Karunakaran, G. (2013). Rambutan cultivation. In W. S. Dhillon (Ed.), Fruit production in India. Narendra Publishing House, Delhi.

[View PDF]         [Google Scholar]

  • Wall, M. M., Sivakumar, D., & Korsten, L. (2011). Rambutan (Nephelium lappaceum L.). In E. M. Yahia (Ed.), Postharvest biology and technology of tropical and subtropical fruits: Mangosteen to white sapote, 312–335. Woodhead Publishing.

[View Chapter]    [Google Scholar]

  • Wahid, P. A., Chopra, R., Kumar, N., Chand, M., Dhiman, A., & Singh, R. (2026). Fibers as oleogelators: Innovations, applications, and future prospects in structured lipid systems. Journal of the American Oil Chemists’ Society, 103, 197–224.

[View Article]      [Google Scholar]

  • Yoswathana, N. (2013). Optimization of ScCO2 extraction of rambutan seed oil using response surface methodology. International Journal of Chemical Engineering and Applications, 4, 187–190.

[View Article]      [Google Scholar]

  • Zatsu, V., Shine, A. E., Tharakan, J. M., Peter, D., Ranganathan, T. V., Alotaibi, S. S., Mugabi, R., Bin Muhsinah, A., Waseem, M., & Nayik, G. A. (2024). Revolutionizing the food industry: The transformative power of artificial intelligence—a review. Food Chemistry: X, 24, 101867.

[View Article]      [Google Scholar]

  • Zzaman, W., Issara, U., Easa, A. M., & Yang, T. A. (2017). Exploration on the thermal behavior, solid fat content and hardness of rambutan fat extracted from rambutan seeds as cocoa butter replacer. International Food Research Journal, 24, 2408–2413.

[View Article]      [Google Scholar]

Cite This Article

S. M. Simon, J. Dayma, “A review of chemistry, extraction, functional properties, and sustainable food applications of rambutan (Nephelium lappaceum L.),” Radius: Journal of Science and Technology 3(2) (2026) 262004. https://doi.org/10.5281/zenodo.22258347

Rights & Permission

This is an open access article published under the Creative Commons Attribution (CC BY) International License, which allows unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. No permission is needed to reuse this content under the terms of the license.
For uses not covered above, please contact the Scholarly Publication Rights Department.